This is what I was looking for, this guys knows his Stuff......... Called BusylittleShop
I coach my customers that instead of looking at brake fluid as
D.O.T. 3/4 versus D.O.T. 5, we should see the issue as glycol versus
silicone. This represents the larger division of type, and comparing
D.O.T. ratings just isn't significant, especially since D.O.T. 5
fluids are now available in glycol formulation. Glycol fluids have
improved until they now meet D.O.T. 5 standards. D.O.T. 5.1 for
example, is a glycol fluid designed for certain ABS systems having
mechanically cycling proportion valves. So now we have D.O.T. 3, 4, 5,
and 5.1, with all but the 5 designation being glycol, while D.O.T 5 is
silicone.
The real way to compare brake fluids is by deciding what is important
to you. Is silicone fluid's safety around paint and plastic more
important than yearly changes and a softer action? Its higher boiling
point, the reason for its development and at one time its strong suit,
is now academic, since D.O.T. 5 glycol (5.1) fluids are now widely
available. Glycol fluid therefore is, for most of us, the better brake
fluid, and the best just may be the 5.1, if the highest boiling point,
which is really a moisture tolerance measurement, matters.
As Glycol progressively contains more moisture it will start to turn
golden, then light brown, Eventually, if left unchanged beyond the
recommended service interval, the fluid will become dark brown,
indicating high amounts of water absorption and thus badly
contaminated fluid... The other problem with this continuous exposure
to moisture is that moisture makes the brake fluid more compressible.
You don't want any compressibility in a brake system. For every
millimeter that the lever moves, you expect a proportionate movement
of the brake pads against the disc. If you don't have that, you have
an unreliable and dangerous brake system. Unfortunately, brake fluid
becomes more compressible as it increases in water content. Water
contains hydrogen, and in response to many heat cycles like at a track
the brake fluid soon has air mixed into it as well as moisture and may
boil... in fact some track day tech inspectors check for brown fluid...
On the practical side, beware that glycol and silicone brake fluids
are hugely incompatible with each other. Mixing even small amounts
will create a sludge that looks amazingly like Italian salad dressing
and is about as effective as a brake fluid
Boiling point of Glycol based brake fluids
DOT 3 205 °C (401 °F)
DOT 4 230 °C (446 °F)
DOT 5 260 °C (500 °F)
DOT 5.1 270 °C (518 °F)
Boiling point of Silicone based brake fluids
DOT 5 260 °C (500 °F)